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You can retrieve the metadata of an S3 Connector by using Workbench.
Complete the prerequisite of Defining the Metadata of S3 Connector
Log in to Workbench, click migration and select Retrieve.

Click Choose File and supply the unpackaged xml. Click Next.
The file referenced in the command must be the name of the unpackage.xml created in Defining the Metadata of S3 Connector step.

Review the staged retrieve request and click Retrieve.
In this screenshot Expand All link is clicked.

Click Download ZIP File and download the retrieved package.

Rename the file recognizably to use in later steps.
Proceed to Update the S3 access key and secret key attributes.